Simultaneous determination of peroxydisulfate and conventional inorganic anions by ion chromatography with the column‐switching technique

The application of ion chromatography with the column‐switching technique for the simultaneous analysis of peroxydisulfate and conventional inorganic anions in a single run is described. With this method, conventional inorganic anions were separated by consecutive elution through both the guard column and separation column, but peroxydisulfate that only passed through the guard column had a good peak shape and short retention time. A series of standard solutions consisting of target anions of various concentrations from 0.01 to 75 mg/L were analyzed, with a correlation coefficient (r) ≥ 0.9990. The limits of detection were in the range of 0.49–9.84 μg/L based on the S/N of 3 and a 25 μL injection volume. RSDs for retention time, peak area, and peak height were all <1.77%. A spiking study was performed with satisfactory recoveries between 97.6 and 103.4% for all anions. The quantitative determination of peroxydisulfate and conventional inorganic anions in surface waters was accomplished within 18 min by this column‐switching technique.     

Microstructure characterization of short-chain branching polyethylene with differential scanning calorimetry and successive selfnucleation/annealing thermal fractionation

A series of the copolymers of ethylene with 1-hexene(M1–M9) synthesized by metallocene catalyst Et[Ind]2ZrCl2/MAO was studied by differential scanning calorimetry and successive self-nucleation and annealing(SSA) thermal fractionation. The distribution of methylene sequence length(MSL) in the different copolymers was determined using the SSA method. The comonomer contents of samples M4 and M5 are 2.04 mol% and 2.78 mol%, respectively. Both M4 and M5 have low comonomer content and their MSL distribution profiles exhibit a monotonous increase trend with their MSL. The longest MSL of M5 is 167, and its corresponding molar percent is 43.95%, which is higher than that of M4. Moreover, the melting temperature(Tm) of M5 is also higher than that of M4. The comonomer contents of samples M7, M8, and M9 are 8.73 mol%, 14.18 mol% and 15.05 mol%, respectively. M7, M8, and M9 have high comonomer contents, and their MSL distribution profiles display unimodality. M7 has a lower peak value of 33 and a narrow MSL distribution, resulting in a Tm lower than that of M8 and M9. The MSL and its distribution are also key points that influence the melting behavior of copolymers. Sometimes, MSL and its distribution of copolymers have a greater impact on it than the total comonomer contents, which is different from traditional views.     

基于序列图像的几何参数测量方法研究

随着测量技术的不断发展,现代工业对物体尺寸检测的准确性及快速性要求越来越高.文中提出了一种利用序列图像来测量物体几何尺寸的方法.使用数码相机获得标定模板的序列图像,通过直接线性变换(DLT)方法来标定相机内部参数,结合透镜成像的知识,对使用数码相机采集到的物体序列图像进行处理和测量,最终计算出物体的宽度和高度.实验证明...     

红外序列图像中运动弱小目标检测

为检测红外序列图像中的运动弱小目标,分析了目标在序列图像中的运动特性和概率分布特性,以及目标和噪声在序列中的能量分布特性。提出连续M帧高阶累积方法来增强运动弱目标能量,用假设检验对目标和背景进行分割,通过搜寻序列运动能量中心来实现目标的多帧关联检测。通过仿真实验证明了算法对红外弱小目标检测有效性。     

Electromechanical cracking in ferroelectrics driven by large scale domain switching

Experimental results indicate three regimes for cracking in a ferroelectric double cantilever beam (DCB) under combined electromechanical loading. In the loading, the maximum amplitude of the applied electric field reaches almost twice the coercive field of ferroelectrics. Thus, the model of small scale domain switching is not applicable any more, which is dictated only by the singular term of the crack tip field. In the DCB test, a large or global scale domain switching takes place instead, which is driven...     

Composition dependence of unipolar resistance switching in TaOx thin films

Amorphous TaO_x thin films were deposited at different temperatures, and the resistance switching properties of the Pt/TaO_x/Pt structure were investigated. X‐ray photoelectron spectroscopy showed that the amount of Ta₂O₅ in the film decreased and the content of Ta suboxides increased substantially when the growth temperature was increased. Unipolar resistance switching near the anode was stable only for TaO_x film grown at room temperature. The experimental results revealed the critical effect of the film composition on the resistance switching behavior of TaO_x films. (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

求m阶递推数列通项公式的两种方法

利用分析中的解析函数方法和代数中的矩阵方法,得到了m阶常系数齐次线性递推数列通项公式的解析表达式,是对已有结果的完善和推广.     

广义活动网络ETI支付进度计划问题的研究

优化ETI支付进度安排是消除承包商和业主由于进度安排原因而产生经济纠纷,实现双赢的最有效方法.本文分析了活动间广义时序关系的类型,建立了广义时序关系下活动间的约束关系;在考虑承包商和业主双方联合收益要求的基础上,提出了双方的净现值按同比例减小的折衷原则,构建了广义活动网络在ETI支付方式下的支付进度计划模型;最后通过一个算例进行了分析,验证表明该优化模型具有较好的有效性和实用性.     

关于迭代数列的审敛法

从迭代数列及其基本性质出发,给出单调有界定理、压缩映象原理、Cauchy收敛准则和上(下)极限四种判别迭代数列收敛的方法.     

Reproducing Kernel method for the solution of nonlinear hyperbolic telegraph equation with an integral condition

In this article, an iterative method is proposed for solving nonlinear hyperbolic telegraph equation with an integral condition. Its exact solution is represented in the form of series in the reproducing kernel space. In the mean time, the n‐term approximation u_n(x, t) of the exact solution u(x, t) is obtained and is proved to converge to the exact solution. Moreover, the partial derivatives of u_n(x, t) are also convergent to the partial derivatives of u(x, t). Some numerical examples have been studied to demonstrate the accuracy of the present method. Results obtained by the method have been compared with the exact solution of each example and are found to be in good agreement with each other. © 2010 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 27: 867–886, 2011